Water compatibility and organic transformations of organo-Zintl deltahedral clusters.
نویسندگان
چکیده
We report the remarkable stability of di-substituted organo-Zintl deltahedral clusters in the presence of water. This has been exploited in a reaction at the organic substituents of the cluster which produces water as a by-product. Also reported are the synthesis, characterization, and crystal structure of [K-krypt](2)[Ge(9)-(CH=CH-CH(2)NH(2))(2)] involved in the reaction.
منابع مشابه
Developing organo-Zintl deltahedral clusters as ligands for coordination to transition-metals via their organic tethers
Deltahedral Zintl ions Ge9 are disubstituted with organic fragments that have various functional groups. Some of the latter are appropriate for coordination to transition-metals to eventually form coordination compounds where the organo-Zintl species act as ligands. Examples of [Ge9R2] include R 1⁄4 eCH]CHIm(Me), eCH]CHeC6H4eOMe, eCH]CH-Fc, eCH]CHe(CH2)4eC^CH, eCH]CHeC6H4eC^CH, CH] CHeC6H4eNH2,...
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 62 شماره
صفحات -
تاریخ انتشار 2012